Microtech 2011

Effect of Thickness based on self-assembly of block copolymer

S.W. Lee, N.R. Park, S.Y. Kim, D.M. Shin
HongKong University, KR

Keywords: block copolymer, photonic crystals, poly(styrene-block-2-pyridine)


Block copolymers have been investigated for fabricating functional nanomaterials due to their properties of self-assembly. We prepared polystyrene-b-poly(2-vinyl pyridine) (PS-b-P2VP) lamellar films which is hydrophobic block-hydrophilic polyelectrolyte block polymer have 57 kg/mol-b-57 kg/mol. The lamellar stacks are obtained by exposing the spin coated film under chloroform. The P2VP blocks were then quaternized and crosslinked to various extents using 5wt% of iodomethane. This study shows that the total film thicknesses change the absorbance band by affecting the thickness of layers consisting of PS-b-P2VP photonic crystals.

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